However, shares of companies related to railways were in keen demand after the government yesterday approved FDI liberalisation in the sector.
The 30-share barometer, which had lost 242.74 points in the previous session, fell by 54.13 points, or 0.21 per cent, to 25,611.14 in early trade.
On similar lines, the broad-based National Stock Exchange index Nifty shed 13.30 points, or 0.17 per cent, to 7,658.75.
Brokers said capital outflows and sustained profit- booking by retail investors amidst weak global cues following signs of deepening Ukraine crisis dampened trading sentiment.
Bucking the trend, shares of companies engaged in railways-related businesses rallied after the Cabinet yesterday fully opened up the railway infrastructure segment, like high-speed trains, for foreign investment.
Titagarh Wagons surged 4.98 per cent, while Kalindee Rail Nirman climbed 5 per cent, and Texmaco Rail zoomed 13.57 per cent. Kernex Microsystems India was up 4.95 per cent.
Among other Asian markets, Hong Kong's Hang Seng fell by 0.35 per cent, while Japan's Nikkei moved down by 0.21 per cent in early trade.
However, the US Dow Jones Industrial Average ended 0.08 per cent higher in yesterday's trade.